Catalytic Asymmetric Carbalkoxyallylation of Imines with the Chiral Bis-π-allylpalladium Complex
- 14 April 2004
- journal article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 69 (10) , 3562-3564
- https://doi.org/10.1021/jo049838l
Abstract
Carbethoxyallylstannane was employed along with the bis-pi-allylpalladium complex to achieve a useful conversion of prochiral imines to chiral 2-(2-aryl-2-aminoethyl)acrylates which are important building blocks for further asymmetric synthesis of a wide range of compounds.Keywords
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