X-Ray Fluorescence Spectroscopy of Metal Sulfides
- 1 March 1978
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 51 (3) , 777-779
- https://doi.org/10.1246/bcsj.51.777
Abstract
The S Kα spectra of the sulfur compounds were measured. The S Kα energies of metal sulfides were less than that of the pure sulfur in accordance with the theoretical prediction. The S Kα shift for CaS (−0.239 eV) is the largest among those of metal sulfides examined in this study. In the sulfur+selenium binary mixtures, the S Kα energy goes more negative than that of sulfur with increasing the selenium content. These results can be interpreted in terms of the electronegativity of the counter atoms.Keywords
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