Formylation of Secondary Amines with Dialkyl Acetals of Dimethylformamide
- 1 January 1980
- journal article
- research article
- Published by Taylor & Francis in Analytical Letters
- Vol. 13 (7) , 625-634
- https://doi.org/10.1080/00032718008077692
Abstract
The product of the reaction of dialkyl acetals of N, N-dimethyl-formamide with desipramine has been found to be N-formyldesipramine, and not the N-ethyl derivative as reported earlier. Evidence for the structure was obtained from NMR, IR and mass spectra of the compound as well as comparison with N-formyl and N-ethyldesipramine prepared by alternate routes.Keywords
This publication has 5 references indexed in Scilit:
- N-Alkylation of Secondary Amine Tricyclic Antidepressants as a General Method for Their Quantitation by GC-MS-SIM Technique. Preparation of N-Ethyl Derivatives of Desimipramine, Nortriptyline, Protiptyline and DesmethyldoxepinAnalytical Letters, 1979
- Mass spectra of partially n-acetylated derivatives of kanamycin aTetrahedron, 1978
- Mechanismus der Amin-eliminierungen bei der Elektronenstoßinduzierten Fragmentierung von 1.3-DiaminopropanenJournal of Mass Spectrometry, 1974
- Amino Acid N-Dimethylaminomethylene Alkyl Esters. New Derivatives for GC and GC-MS StudiesAnalytical Letters, 1972
- Reaktionen mit AlkylkationenEuropean Journal of Inorganic Chemistry, 1956