Triangular Assembly Through Charged Hydrogen Bonds in Polar Solvent
- 25 October 2006
- journal article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 71 (24) , 9225-9228
- https://doi.org/10.1021/jo061543f
Abstract
We have demonstrated a triangular assembly driven by 12 charged hydrogen bonds and π−π interactions. This assembly is stable even in polar solvents because of its charged hydrogen-bond nature. Helical arrangement of the complex is confirmed by its crystal structure. A solution structure is assigned to the D3 isomer corresponding to the solid-state structure by temperature-dependent 1H NMR experiments.Keywords
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