Self-Assembling of n-Type Semiconductor Tri(phenanthrolino)hexaazatriphenylenes with a Large Aromatic Core
- 25 January 2006
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 8 (4) , 585-588
- https://doi.org/10.1021/ol052779t
Abstract
[reaction: see text] Large disk-shaped aromatic tri(phenanthrolino)hexaazatriphenylenes 5a, 5b, and 5c with six butyl, dodecyl, and 4-octylphenyl groups, respectively, were self-assembled both in solution and film state to form one-dimensional aggregates. Their n-type semiconducting nature was indicated from CV measurement, in which the first reduction potentials were evaluated at around -1.7 V (vs Fc/Fc(+)) in dichloromethane.Keywords
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