Structure and Properties of Halogeno(hydrido)(triorganosilyl)rhodium(III) Complexes, RhX(H)(SiR1nR23-n)(PPh3)2(X = Cl, I; R1= OSiMe3, OEt, R2= Me). Influence of the Alkoxy Groups and Halo Ligand on Stability and Reactivity of the Complexes
- 1 February 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 21 (5) , 825-831
- https://doi.org/10.1021/om010862o
Abstract
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This publication has 45 references indexed in Scilit:
- Thermal Si−C Bond Cleavage of LRhH(SiAr3)(μ-H)(μ-Cl)RhH(SiAr3)L (Ar = C6H5, C6H4F-p; L = P(i-Pr)3) To Give LRhH(μ-SiAr3)(μ-SiAr2)(μ-Cl)RhHL Containing Symmetrically Bridging Triarylsilyl and Diarylsilylene LigandsOrganometallics, 1998
- RhCl(PPh3)3/NaI Catalyst System for Hydrosilylation of 1-Alkynes: Stereodivergent Syntheses of E- and Z-Alkenylsilanes with Heteroatom Substituents on SiliconChemistry Letters, 1998
- Isomers of Chloro(triarylsilyl)hydridorhodium(III) Complexes, mer-RhCl(H)(SiAr3)(PMe3)3. Relevance of Their Structures to Reductive Elimination of ClSiAr3Organometallics, 1998
- A Symmetrically Bridging Triarylsilyl Ligand in a Dinuclear Rhodium Complex: Synthesis and Structure of [LRh(H)(µ-Cl)(µ-SiAr2)(µ-SiAr3)Rh(H)L] (Ar=Ph,p-FC6H4; L=PiPr3)Angewandte Chemie International Edition in English, 1998
- Structure and Chemical Properties of Chlorohydrido(diarylsilyl)rhodium(III) Complexes,mer-RhCl(H)(SiHAr2)(PMe3)3. Thermally Induced Chloro Transfer from Rhodium to Silicon in the Complexes and Silane ExchangeOrganometallics, 1997
- Si–H and Si–C Bond Activation of a Triorganosilane Promoted by [RhCl{P(i-Pr)3}2]. Synthesis and Structure of a Dinuclear Rh(IV) Complex with μ-Silylene LigandsBulletin of the Chemical Society of Japan, 1997
- Structure and reactivity of a (triphenylsilyl)rhodium(I) compoundInorganic Chemistry, 1990
- Reactions of primary and secondary silanes with binuclear rhodium complexes. Formation of .mu.-silylene complexes and phosphorus-silicon bonds with facile phosphorus-carbon bond cleavageJournal of the American Chemical Society, 1990
- Reaction of primary silanes with a binuclear rhodium complex. Formation of .mu.-silylene complexes and rapid silicon-hydrogen/rhodium-hydrogen exchangeOrganometallics, 1988
- Homogeneous Catalysis. II. The Mechanism of the Hydrosilation of Olefins Catalyzed by Group VIII Metal Complexes1Journal of the American Chemical Society, 1965