The synthesis and low-temperature single crystal X-ray structure of the charge-transfer complex ([9]aneS3)2(l2)4([9]aneS3= 1,4,7-trithiacyclononane)

Abstract
Reaction of [9]aneS3(1,4,7-trithiacyclononane) and I2 in cold CH2Cl2 results in the formation of 1 :1 and 1 : 2 adducts; the single crystal X-ray structure of the 1 :2 adduct ([9]aneS3)3(I2d2)4 shows an unusual polymeric structure with I2 bridging [9]aneS3 thioether units.

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