Azide Substitution at Mannose Derivatives. A Potential New Route to Glucosamine Derivatives
- 1 January 1984
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 3 (1) , 117-124
- https://doi.org/10.1080/07328308408057901
Abstract
Since the pioneering work of Paulsen et al.1 on stereoselective coupling reactions of glucosamine derivatives, the azide function has found general application in carbohydrate chemistry as a nonparticipating masking group for amines. Although excellent results have been reported for the synthesis of α-coupled glucosamine derivatives, the preparation of the required 2-azido-2-deoxy- -glucopyranose is often laborious.1cKeywords
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