Calculation of correlation functions of hard spheres in the generalized mean spherical approximation
- 1 September 1983
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 28 (3) , 1700-1708
- https://doi.org/10.1103/physreva.28.1700
Abstract
Wiener-Hopf factorization technique as suggested by Baxter has been used to solve the Ornstein-Zernike equation for a system of hard spheres in the framework of a generalized mean spherical model. The method reported here yields unambiguous and accurate values of the radial distribution function , direct correlation function , and the structure function . These thermodynamic quantities have been calculated from low to fairly high densities and, with a normalized , they have been compared with the molecular-dynamics values of Alder and Hecht.
Keywords
This publication has 18 references indexed in Scilit:
- Statistical mechanics of simple fluids: beyond van der WaalsPhysics Today, 1980
- Theory of simple classical fluids: Universality in the short-range structurePhysical Review A, 1979
- What is "liquid"? Understanding the states of matterReviews of Modern Physics, 1976
- Charged hard spheres in a uniform neutralizing background using ‘mixed’ integral equationsMolecular Physics, 1976
- The solid-fluid phase transition: contribution of small watermelonsJournal of Physics C: Solid State Physics, 1974
- Mean Spherical Model for Lattice Gases with Extended Hard Cores and Continuum FluidsPhysical Review B, 1966
- Equation of State for Hard SpheresThe Journal of Chemical Physics, 1963
- Exact Solution of the Percus-Yevick Integral Equation for Hard SpheresPhysical Review Letters, 1963
- A New Approach to the Theory of Classical Fluids. IProgress of Theoretical Physics, 1960
- Analysis of Classical Statistical Mechanics by Means of Collective CoordinatesPhysical Review B, 1958