Simple, high-yields syntheses of nickel-osmium clusters. spectroscopic characterization of the new (η-C5H5)NiOs3(CO)9(μ2-H)3. The reactivity of (η-C5H5)NiOs3(CO)9(μ2-H)3 and (η-C5H5)3Ni3Os3(CO)9 towards H2, CO, alkynes and alkenes
- 4 January 1983
- journal article
- Published by Elsevier in Journal of Organometallic Chemistry
- Vol. 241 (1) , 99-111
- https://doi.org/10.1016/0022-328x(83)80029-1
Abstract
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This publication has 14 references indexed in Scilit:
- The reactivity of HRu3(CO)9C2·CMe3. The hydrogenation of coordinated t-butyl-acetylene to neo-hexane and the crystal structure of the intermediate trihydride H3Ru3(CO)9C·CH2·CMe3Inorganica Chimica Acta, 1981
- The reactions of ruthenium carbonyl and alkyne-carbonyl complexes with nickelocene, [(η-C5H5)Ni(CO)]2 and (η-C5H5)2Ni2(RC2R′). Cyrstal structures of two isostructural heterometallic trinuclear clusters, (η-C5H5)2Ni2Ru(CO)3(C2Ph2) and (η-C5H5)2Ni2Fe(CO)3(C2Ph2)Journal of Organometallic Chemistry, 1981
- Synthesis and crystal structure of a new mixed-metal cluster, (η-C5H5)3Ni3Os3(CO)9. An example of a high yield pyrolytic synthesisJournal of the Chemical Society, Chemical Communications, 1981
- The reactions of iron-carbonyl and alkyne-carbonyl complexes with nickelocene, [(η-C5H5)Ni(CO)]2 and (η-C5H5)2Ni2(RC2R'). crystal structures of two heterometallic tetranuclear clustersJournal of Organometallic Chemistry, 1980
- the reactivity of HRu3(CO)9C2But. Synthesis and crystal structure of (η5-C5H5)NiRu3(CO)9CsdC(H)But, a new mixed ruthenium-nickel clusterInorganica Chimica Acta, 1980
- Preparation and X-ray structure determination of the mixed cluster [H3CoOs3(CO)12]Journal of the Chemical Society, Chemical Communications, 1978
- Addition reactions of a polynuclear osmium hydrido compound leading to associative carbonyl substitution and catalytic alkene isomerisationJournal of Organometallic Chemistry, 1976
- The interaction of decacarbonyldihydrotriosmium with alkenes. Intermediates in hydrogenation and carbon-hydrogen bond activationJournal of the American Chemical Society, 1976
- Structure of H3Os3(CO)9CCH3 by nemetic-phase pmr and x-ray powder photographyJournal of Organometallic Chemistry, 1974
- Location of the hydrogen atoms in dodecarbonyltrihydromanganese. Crystal structure determinationJournal of the American Chemical Society, 1973