Analysis of a Model Exhibiting Condensation with Application to
- 3 June 1966
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 146 (1) , 101-109
- https://doi.org/10.1103/physrev.146.101
Abstract
A study is made of a certain model Hamiltonian which describes a system of fermions. Making use of the variational results of Girardeau one can obtain, in the limit of infinite volume, an explicit formula for the free energy in terms of the solution of a nonlinear integral equation. It is established that for certain values of the coupling constant the model exhibits condensation, and that qualitatively at least, the isotherms for the model reproduce those for actual physical systems. The model is applied to and it is shown that by a suitable choice for the parameters of the model, reasonable agreement with the low-temperature properties of is obtained. The second virial coefficient for is also reproduced with the same parameter values which give the correct virial coefficient for .
Keywords
This publication has 11 references indexed in Scilit:
- Transport Properties of GaseousandPhysical Review B, 1965
- Phase Transitions in Systems of Interacting FermionsPhysical Review B, 1965
- Stability of the thermal Hartree-Fock approximationAnnals of Physics, 1963
- Variational Method for the Quantum Statistics of Interacting ParticlesJournal of Mathematical Physics, 1962
- The equation of state of gases at low temperaturesPhysica, 1958
- Pressure-Volume Isotherms ofbetween 1.5 and 3.8°KPhysical Review B, 1955
- Second Virial Coefficients of Helium from the Exp-Six PotentialPhysical Review B, 1955
- Pressure-Volume Isotherms ofbelow 4.2°KPhysical Review B, 1955
- On a Minimum Property of the Free EnergyPhysical Review B, 1938
- Nichtlineare Integralgleichungen nebst AnwendungenActa Mathematica, 1930