Formation and chemical behaviour of silylated phosphanes
- 19 December 1983
- journal article
- research article
- Published by Taylor & Francis in Phosphorus and Sulfur and the Related Elements
- Vol. 18 (1) , 65-68
- https://doi.org/10.1080/03086648308075968
Abstract
Our investigations to be presented here have their origin in a number of former results: The formation of [(Me3Si)2P]2SiMe2 [1] and its rearrangement to P4(SiMe2)6 (a molecule with adamantane structure) and P(SiMe3)3, the formation of P7(SiMe3)3 and of some cyclic phosphanes by the thermally induced rearrangement of [(Me3Si)2)P]2SiMe2 [3], and the formation of P7(SiMe3)3 by reacting P4 with Na/K-alloy and Me3SiCl. After finding LiP(SiMe3)2 to be such a versatile reagent we turned to elucidate synthesis and chemical behaviour of LiP[P(SiMe3)2]2.Keywords
This publication has 3 references indexed in Scilit:
- Zur Bildung linearer und cyclischer PhosphaneZeitschrift für anorganische und allgemeine Chemie, 1979
- Das Dodekamethyl‐hexasila‐tetraphosphaadamantan (me2Si)6P4Zeitschrift für anorganische und allgemeine Chemie, 1978
- Zur Bildung von Disilylphosphino-Element-Verbindungen des C, Si, PZeitschrift für anorganische und allgemeine Chemie, 1977