Regioselective 12CO/13CO exchange activity of a mixed-valent Fe(ii)Fe(i) model of the Hox state of [FeFe]-hydrogenase

Abstract
A mixed-valent Fe(II)Fe(I) model of the Hox state of [FeFe]-hydrogenase is shown, under certain conditions, to exhibit regioselective 12CO/ 13CO exchange activity similar to that observed for Hox .

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