Synthesis of α-Metoylene-γ-Lactones in Furanosidic Systems
- 1 May 1987
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 6 (2) , 259-272
- https://doi.org/10.1080/07328308708058875
Abstract
Synthesis of stereoisomeric α-methylene-γ-lactones in furanose-and furanuronoamide derivatives was easily accomplished by Reformatsky Reaction with ethyl bromcmethylacrylic ester and zinc. Pyridinium chlorochromate/3Å molecular sieve powder showed to be an excellent reagent for the oxidation of secondary hydroxyl groups of a furanose system and of α-hydroxy amides.This publication has 22 references indexed in Scilit:
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