Réactions D'amines Germaniées avec les Aldéhydes et les Cétones
- 1 January 1970
- journal article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 89 (12) , 1281-1296
- https://doi.org/10.1002/recl.19700891209
Abstract
The insertion of aldehydes and ketones onto the germanium‐nitrogen bond of trialkylgermylamines leads to α‐aminoalkoxygermanes which are generally not very stable.Their decomposition leads to trialkylgermanium oxides and enamines or imines corresponding to the aminogermanes and carbonyl derivatives.The formation of enamine or imine takes place through gem‐diamines which are usually unstable. The derivatives obtained by insertion of the halogenated aldehydes and ketones such as chloral and hexachloroacetone decompose through β‐elimination, with formation of trialkyl(trichloromethyl)germane R3GeCCl3, trialkylchlorogermane and dichlorocarbene.Keywords
This publication has 13 references indexed in Scilit:
- Réactions de l'acétone avec des amines stanniquesJournal of Organometallic Chemistry, 1969
- Réactions du diéthylaminotributylétain avec certaines cétones cyclaniques et aliphatiquesJournal of Organometallic Chemistry, 1969
- Amido-derivatives of metals and metalloids. Part IX. Reactions of tin(IV) and titanium(IV) amides with compounds having carbonyl and sulphinyl multiple bondsJournal of the Chemical Society C: Organic, 1969
- Germanotropic EquilibriumJournal of Organometallic Chemistry, 1968
- Studies in the enamine field—XXIXTetrahedron, 1968
- Reactions of group IV organometallic compounds IX addition and subsequent β-elimination reactions of trimethylsilyl- and stannylamines with chloralTetrahedron Letters, 1968
- Perhalogeno-ketone fissions of Si–N, Ge–N, and Sn–N bondsJ. Chem. Soc. A, 1968
- Studies in the enamine field reactions between acetone diethylketal and secondary aminesTetrahedron Letters, 1966
- Preparation and Chemistry of α-Chloroalkyllithium Compounds. Their Role as Carbenoid Intermediates1Journal of the American Chemical Society, 1965
- Amino derivatives of metals and metalloids : III. Metal amines as reagents for synthesis of organometallics; especially the reactions of aminostannanes with protic speciesJournal of Organometallic Chemistry, 1965