Selective Retention for Structural Isomers in Aqueous Liquid Chromatography Using Poly(γ-Methyl L-Glutamate) Spherical Particles

Abstract
Poly(γ-methyl L-glutamate) spherical particles having micropores showed higher retention capacity for n-isomers of alcohols (with remarkable temperature dependencies) than for tert-isomers in the aqueous liquid chromatography. No similar temperature dependence was observed for either spherical particles having macropores or alkyl-bonded silica gels.