Chronometric calibration of mid-Ordovician to Tournaisian conodont zones: a compilation from recent graphic-correlation and isotope studies

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Abstract
Three available graphic-correlation analyses are used to calibrate mid-Palaeozoic conodont zonations: Sweet's scheme for the mid- to Upper Ordovician; Kleffner's for the mid- to Upper Silurian; and Murphy & Berry's for the lower and middle Lower Devonian. The scheme of Sweet is scaled by applying the high-precision U-Pb zircon date of Tucker and others for the Rocklandian and linked with that of Kleffner by scaling the graptolite sequence of the Ordovician-Silurian global stratotype section to fit two similarly derived dates from this sequence. The top of Kleffner's scheme, all of Murphy & Berry's, as well as standard zones to the Frasnian are calibrated by using tie-points of the latest Cambridge-BP time-scale (GTS 89). However, the recent microbeam zircon date by Claoué-Long and others for the Hasselbachtal Devonian-Carboniferous auxiliary stratotype is used to calibrate the standard Famennian zones. Also the similarly derived but preliminary determination reported by Roberts and others from the Isismurra Formation of New South Wales is tentatively taken as the top of the Tournaisian and so used to calibrate Tournaisian zones. Despite the considerable extrapolation required to compile these schemes and their inherent errors, the resultant time-scale closely agrees with other dates of Tucker and others from the Llanvirn as well as the GTS 89 Homerian-Gorstian tie-point. This suggests that stratigraphic methods can be usefully applied to geochronometry. The Llandovery appears to have lasted longer (16 m. y.) than usually envisaged and the Ordovician-Silurian boundary may need to be lowered to approximately 443.5 Ma. Certainly, chrons varied widely in duration and further stratigraphic studies to estimate their relative durations as well as high-resolution dating for their calibration will be crucial to more accurate biochronometries.