Ferromagnetic Coupling through Spin Polarization in a Dinuclear Copper(II) Metallacyclophane
- 15 August 2001
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 40 (16) , 3039-3042
- https://doi.org/10.1002/1521-3773(20010817)40:16<3039::aid-anie3039>3.0.co;2-p
Abstract
First organic radicals, now metal complexes: A successful extension to metal complexes of a well-known organic radical approach to ferromagnetism is exemplified by the triplet ground-state molecule containing two CuII centers connected by a double m-phenylenediamide skeleton of the cyclophane type shown in the scheme.Keywords
This publication has 30 references indexed in Scilit:
- Spinpolarisierung und Ferromagnetismus in zweidimensionalen CoII-Schichtpolymeren: [Co(L)2(NCS)2] (L = Pyrimidin, Pyrazin)Angewandte Chemie, 1998
- Effects of Systematic Variation in Bridging Ligand Structure on the Electrochemical and Magnetic Properties of a Series of Dinuclear Molybdenum ComplexesInorganic Chemistry, 1996
- Control of Intramolecular Magnetic Interaction by the Spin Polarization of d.pi. Spin to p.pi. Orbital of an Organic Bridging LigandThe Journal of Physical Chemistry, 1995
- Magnetism of Heterobimetallics: Toward Molecular-Based MagnetsAdvances in Inorganic Chemistry, 1995
- Organic and Organometallic Molecular Magnetic Materials—Designer MagnetsAngewandte Chemie International Edition in English, 1994
- Organische und metallorganische molekulare magnetische Materialien: Designer‐MagneteAngewandte Chemie, 1994
- Pyrimidines as Ferromagnetic Exchange Couplers in Dinuclear Oxovanadium(IV) ComplexesChemistry Letters, 1994
- Ferromagnetic spin alignment in molecular systems: an orbital approachAccounts of Chemical Research, 1993
- Dinuclear Complexes with Predictable Magnetic PropertiesAngewandte Chemie International Edition in English, 1985
- Zweikernkomplexe mit vorhersagbaren magnetischen EigenschaftenAngewandte Chemie, 1985