endo/exo Isomerism in Norcarane and 2-Norcaranol Hydrotrioxides (ROOOH)
- 11 October 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 68 (23) , 9129-9131
- https://doi.org/10.1021/jo035154m
Abstract
Ozonation of norcarane (1) yielded endo and exo norcarane hydrotrioxides (2a, 2b), as characterized by 1H and 13C NMR spectroscopy. Further ozonation of the primary decomposition products of these hydrotrioxides, i.e., 2-norcaranols (3), produced the corresponding isomeric 2-norcaranol hydrotrioxides (4a, 4b), and hydrogen trioxide (HOOOH).Keywords
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