Pressure induced shifts in HCl/HF and HF/HCI systems
- 1 January 1981
- journal article
- Published by EDP Sciences in Journal de Physique
- Vol. 42 (2) , 203-208
- https://doi.org/10.1051/jphys:01981004202020300
Abstract
As a sequel to a previous theoretical study of pressure induced lineshifts in the spectra of diatomic molecules pressurized by polar gases, some new experimental results became recently available and are reported in this paper. They concern the shifts in the HF(0-2) band due to HCl, and the HCl(0-1) and HCl(0-2) bands due to HF, for which predictions have been previously published. In the present paper, theoretical calculations have been again performed for these systems, starting from a formalism developed by Robert and Bonamy, which improves the Anderson theory. By taking into account, as shown previously, the non commutative character of the intermolecular potential, in the calculation of the differential cross-section, a good quantitative agreement with experiments has been obtained for all the considered casesKeywords
This publication has 13 references indexed in Scilit:
- Short range force effects in semiclassical molecular line broadening calculationsJournal de Physique, 1979
- Measurements of pressure-induced shifts in the 1-0 and 2-0 bands of HF and in the 2-0 bands of H35Cl and H37ClJournal of Quantitative Spectroscopy and Radiative Transfer, 1978
- Shifts of the vibration–rotation absorption lines of diatomic molecules perturbed by diatomic polar molecules. A theoretical analysisThe Journal of Chemical Physics, 1976
- A semiclassical theory for spectral line broadening in moleculesThe Journal of Chemical Physics, 1976
- Rotation and Rotation-Vibration Pressure-Broadened Spectral LineshapesAnnual Review of Physical Chemistry, 1974
- Intermolecular Potentials and Width of Pressure-Broadened Spectral Lines. I. Theoretical FormulationThe Journal of Chemical Physics, 1969
- Collision Broadening of Rotational Absorption Lines. I. Theoretical FormulationThe Journal of Chemical Physics, 1967
- Pressure-Induced Shifts of Hydrogen Fluoride Lines Due to Noble GasesThe Journal of Chemical Physics, 1965
- Line-widths of pressure-broadened spectral linesJournal of Quantitative Spectroscopy and Radiative Transfer, 1962
- Pressure Induced Shifts of HCl Absorption Lines in the InfraredThe Journal of Chemical Physics, 1959