REACTIONS OF SUGAR CHLOROSULFATES: PART VI. THE STRUCTURE OF UNSATURATED CHLORODEOXY SUGARS
- 1 November 1965
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 43 (11) , 3018-3025
- https://doi.org/10.1139/v65-416
Abstract
Methyl α- and β-L-arabinopyranosides when treated with sulfuryl chloride yielded methyl 4-chloro-4-deoxy-α-D-xylopyranoside 2,3-dichlorosulfate and methyl 3,4-dichloro-3,4-dideoxy-β-D-ribopyranoside 2-chlorosulfate respectively. L-Arabinose gave, in addition to 4-chloro-4-deoxy-D-xylosyl chloride 2,3-dichlorosulfate, an unsaturated tetrachloro–tetradeoxy dimer. The structure and mode of formation of these compounds is discussed.Keywords
This publication has 3 references indexed in Scilit:
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- THE REACTION OF SULPHURYL CHLORIDE WITH REDUCING SUGARS: PART ICanadian Journal of Chemistry, 1962
- The Reductive Cleavage of Ozonides to AlcoholsThe Journal of Organic Chemistry, 1960