Synthesis and Metal Complexation of Avic-Dioxime Derivative of Calix [6] Arene
- 1 January 1993
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 23 (1) , 67-75
- https://doi.org/10.1080/15533179308016617
Abstract
A vic-dioxime derivative of calix[6]arene was synthesized from anti-chloroglyoxime and 5,11,17,23,29,35-hexamino-37,38,39,40,41,42-hexamethoxy-calix [6] arene. The prepared compound has six vic-dioxime groups and its complexes have a metal-ligand ratio of 3:1. The Cu(II) and Ni(II) complexes of the ligand are square-planar, while the Co(II) complex is octahedral with water molecules as axial ligands.Keywords
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