Novel 1:1 Complex of Rhodium(III)porphyrins with Nucleobases
- 1 January 1990
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 19 (1) , 51-54
- https://doi.org/10.1246/cl.1990.51
Abstract
Axial ligation behaviors of nucleobases to Rh(III)porphyrins were investigated. Except the case of TPP·Rh(III)-1-methylthymine system, tight 1:1 complexations were observed between Rh(III)porphyrins and nucleobases and their binding constants were determined by spectroscopic titration.Keywords
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