A New Synthetic Approach to Boron Triisothiocyanate-Tertiary Amine Adducts and Related Species
- 1 August 1991
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 21 (8) , 1133-1139
- https://doi.org/10.1080/15533179108020210
Abstract
The reaction of the adduct BDMA.BC13 (BDMA = N.N dimethylbenzylamine) with KNCS in refluxing, toluene, with tetraglyme added, was found as a very convenient route to BDMA.B(NCS)3. Further, according to the stoichiometry, either mixed species BDMA.BC1n(NCS)3-n(n = 1,2) or K+|B(NCS)4|−, were also obtained. The same reaction was applied to KF and KNCO as well as to other tertiary alkylamines.Keywords
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