Oxidative Carbon−Carbon Bond Formation via Silyl Bis-enol Ethers: Controlled Cross-Coupling for the Synthesis of Quaternary Centers
- 1 October 2007
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 9 (22) , 4667-4669
- https://doi.org/10.1021/ol702306z
Abstract
Unsymmetrical silyl bis-enol ethers have been developed as effective substrates for synthesizing quaternary centers from tetralone derivatives through oxidative carbon-carbon bond formation. The derived products are shown to be highly versatile intermediates that may be used to generate diverse structures such as cyclopentenones, 2H-pyrroles, and spirocyclic pyrrolidines.Keywords
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