Cross-relaxation determination of short quadrupolar spin–lattice relaxation rates in solids: Strong mixing in KH2AsO4 and Ag2H3IO6

15 April 1975

journal article
research article
Published by AIP Publishing in The Journal of Chemical Physics

Vol. 62 (8) , 3118-3121
https://doi.org/10.1063/1.430912

Abstract

The application of dipolar proton (I) spin–lattice relaxation time measurements for the determination of fast quadrupolar spin–lattice relaxation rates on nonresonant S spins, the signals of which are too weak to be measured directly, are discussed in the limit of strong I–S dipolar coupling. The spin–lattice relaxation of the common ¹H–⁷⁵As dipolar reservoir in KH₂AsO₄ and the common ¹H–¹²⁷I dipolar reservoir in Ag₂H₃IO₆ are used to illustrate the above technique.

Keywords

This publication has 3 references indexed in Scilit:

Cross-Relaxation Determination of Short Quadrupolar Spin-Lattice Relaxation Rates in Solids: Proton-Iodine Cross Relaxation in Antiferroelectric ${Ag}_{2}$ $H_{3}$ I $O_{6}$ and ${(N H_{4})}_{2}$ $H_{3}$ I $O_{6}$
Physical Review B, 1973
75As spin-lattice relaxation and resonance in KH2AsO4 type ferroelectric crystals
The Journal of Chemical Physics, 1973
Temperature Dependences of the Nuclear Quadrupole Resonance Spectra of As⁷⁵ in KH₂AsO₄, RbH₂AsO₄, CsH₂AsO₄, NH₄H₂AsO₄, and of their Deuterated Analogues
Physica Status Solidi (b), 1968