Solvent Effects on the Infrared Spectra of Organophosphorus Compounds
- 1 January 1963
- journal article
- research article
- Published by SAGE Publications in Applied Spectroscopy
- Vol. 17 (1) , 12-14
- https://doi.org/10.1366/000370263774415533
Abstract
Solvent effects on the P → O and [p → 0]G absorptions in organophosphorus compounds of the type (GO)3P → O, (GO)3G'P→ O, [(GO)G'PO(OH)]2, [(GO)3PO(OH)]2, and G3P → O are described, where G is an alkyl or aryl group. The unassociated phosphoryl dipoles are affected by solvents in a manner similar to the carbonyl dipole The consequences of the solvent effects on the physical properties of these compounds are discussed.Keywords
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