Convergence of Magnus and Magnus-like expansions in the Schrödinger representation
- 15 October 1986
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 85 (8) , 4605-4613
- https://doi.org/10.1063/1.451781
Abstract
General and greatly simplified methods are presented for calculating terms in the exponent in Magnus and Magnus‐like expansions to first order in a ‘‘small’’perturbation and to infinite order in the overall Hamiltonian in the Schrödinger representation. These techniques are applied to four simple but important models and it is shown that in each case the Magnus exponent diverges for some range of the parameters of the model. This result casts serious doubt on the utility of the Magnus expansion in the Schrödinger representation. Several of the problems are also treated in the interaction representation giving results which converge throughout the useful range of parameters. There is no evidence that a similar question exists in this representation.Keywords
This publication has 30 references indexed in Scilit:
- Two-state systems in semiclassical and quantized fieldsThe Journal of Physical Chemistry, 1984
- Study, extension, and application of Floquet theory for quantum molecular systems in an oscillating fieldPhysical Review A, 1983
- Application of average Hamiltonian theory to the NMR of solidsPhysical Review B, 1982
- Quasistationary magnetization in pulsed spin-locking experiments in dipolar solidsPhysical Review B, 1980
- Erratum: Semiclassical calculations on one-, two-, three-, and four-photon absorption in truncated models of the hydrogen atomPhysical Review A, 1978
- Rotational spectral line broadening of OCS by noble gasesThe Journal of Chemical Physics, 1974
- Coherent Averaging Effects in Magnetic ResonancePhysical Review B, 1968
- Solution of the Schrödinger Equation with a Hamiltonian Periodic in TimePhysical Review B, 1965
- On the exponential solution of differential equations for a linear operatorCommunications on Pure and Applied Mathematics, 1954
- Space Quantization in a Gyrating Magnetic FieldPhysical Review B, 1937