Heteronuclear double resonance studies of trisilylphosphine and trisilylstibine
- 1 January 1971
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 20 (2) , 317-320
- https://doi.org/10.1080/00268977100100291
Abstract
The relative signs of all the coupling constants involving 1H, 29Si and 31P in (28SiH3)2P29SiH3 and (28SiH3)2Sb29SiH3 have been determined by 1H-{29Si} and 1H-{31P} ‘tickling’ experiments. With the exception of 1 K(29Si-31P), the reduced coupling constants are probably positive over one and three bonds, and negative over two and four bonds.Keywords
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