Mild and efficient palladium(ii)-catalyzed racemization of allenes
- 9 March 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 8,p. 964-965
- https://doi.org/10.1039/b316482a
Abstract
Allenes undergo racemization in the presence of catalytic amounts of Pd(OAc)2/LiBr under mild conditions; the reaction proceeds via a bromopalladation–debromopalladation sequence and tolerates various functional groups.Keywords
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