Supramolecular synthons based on N–H⋯N and C–H⋯O hydrogen bonds. Crystal engineering of a helical structure with 5,5-diethylbarbituric acid
- 18 July 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 17,p. 1830-1831
- https://doi.org/10.1039/b204388b
Abstract
5,5-Diethylbarbituric acid is a convenient molecular precursor for a newly identified N–H⋯N/C–H⋯O synthon, which is robust enough for the design of a helix architecture.Keywords
This publication has 9 references indexed in Scilit:
- Helix versus zig-zag: control of supramolecular topology via carboxylic acid conformations in ortho-substituted phenyl aminesChemical Communications, 2002
- “Total Synthesis” Supramolecular Style: Design and Hydrogen-Bond-Directed Assembly of Ternary SupermoleculesAngewandte Chemie International Edition in English, 2001
- Crystallization of Pseudopolymorphs of Some Gamboge Pigments. Pyridine, Dimethylformamide and Dimethylsulfoxide Solvates of Morellic Acid, Gambogic Acid and Guttiferic AcidSupramolecular Chemistry, 2001
- Crystal engineering using co‐crystallisation of phenazine with dicarboxylic acidsJournal of Materials Chemistry, 2000
- Systematic analysis of the probabilities of formation of bimolecular hydrogen-bonded ring motifs in organic crystal structuresNew Journal of Chemistry, 1999
- Crystal Engineering Using Bisphenols and Trisphenols. Complexes with Hexamethylenetetramine (HMTA): Strings, Multiple Helices and Chains-of-Rings in the Crystal Structures of the Adducts of HTMA with 4,4'-Thiodiphenol (1/1), 4,4'-Sulfonyldiphenol (1/1), 4,4'-Isopropylidenediphenol (1/1), 1,1,1-Tris(4-hydroxyphenyl)ethane (1/2) and 1,3,5-Trihydroxybenzene (2/3)Acta crystallographica Section B, Structural science, crystal engineering and materials, 1997
- X-Ray crystal structure of C6H3(CO2H)3-1,3,5·1.5(4,4′-bipy): a ‘super trimesic acid’ chicken-wire gridChemical Communications, 1996
- Creation of crystalline supramolecular assemblies using a C–H⋯O/O–H⋯N pair-wise hydrogen bond couplingChemical Communications, 1996
- Supramolecular Synthons in Crystal Engineering—A New Organic SynthesisAngewandte Chemie International Edition in English, 1995