Rotationally induced transitions in close encounters of one-electron collisional systems: the three-state problem
- 14 November 1982
- journal article
- Published by IOP Publishing in Journal of Physics B: Atomic and Molecular Physics
- Vol. 15 (21) , 3871-3880
- https://doi.org/10.1088/0022-3700/15/21/011
Abstract
Transitions induced by rotation of the internuclear axis in close collisions of atomic particles at low energies are investigated within the one-electron united-atom approximation. The three-state problem ( sigma to pi , delta transitions) is treated in more detail. Effects arising as a consequence of a different choice of classical trajectories of the nuclei are demonstrated in the example of 3d sigma to 3d pi , 3d delta transitions, contributing to the Li3++H to Li2++H+ charge-exchange reaction.Keywords
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