Kinetic resolution of (±)-cyclohex-1-enylsilanols by the sharpless asymmetric epoxidation
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 436-437
- https://doi.org/10.1039/c39930000436
Abstract
Unprecedented kinetic resolution of (±)-cyclohex-1-enylsilanols 1 by the Sharpless asymmetric epoxidation has been accomplished, the rate difference between enantiomers, krel, being >11 to give enantiomerically pure cyclohex-1-enylcyclohexylmethylsilanol 1b in a particular case.Keywords
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