Critical behavior of ionic-fluid models
- 1 May 1992
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 45 (10) , 7628-7631
- https://doi.org/10.1103/physreva.45.7628
Abstract
It is argued that one should expect a fluid of symmetrically charged hard spheres (the restricted primitive model) to have an Ising-like critical point. It is further noted that the presence of a repulsive ion-ion interaction term (of the sort found in real ionic systems as a result of solvent-averaged ion-dipole-ion interaction) will prevent such a critical point from developing, although competing terms that suppress its effect may also be present in real electrolytes.
Keywords
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