Hyperfine Interactions in the 5d Transition Series
- 1 March 1970
- journal article
- conference paper
- Published by AIP Publishing in Journal of Applied Physics
- Vol. 41 (3) , 1321-1322
- https://doi.org/10.1063/1.1658922
Abstract
Hyperfine interactions at nuclei of 5d transition ions have been studied by means of spin‐unrestricted Hartree‐Fock (SUHF) calculations. For the divalent ions Hf2+ through Pt2+, the core polarization field per unpaired spin is constant to within 9%, varying from −700 to −760 kG. Comparison is made with the few NMR, EPR, and Mössbauer experiments available to date. Fair agreement is found between theory and experiment, indicating the need for more experiments and additional information about relativistic contributions to the hyperfine interaction.This publication has 4 references indexed in Scilit:
- X-Ray Photoelectron Spectroscopic Study of Iron, Cobalt, Nickel, Copper, and PlatinumPhysical Review Letters, 1968
- Magnetic Moments of Rhenium-186 and Rhenium-188 and Analysis of the Rhenium Hyperfine StructurePhysical Review B, 1965
- Interpretation of Knight Shifts and Susceptibilities of Transition Metals: PlatinumPhysical Review B, 1964
- Complex hyperfine structures in microwave spectra of covalent iridium compoundsProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1954