Confirmation of SF3+ Vibrational Assignments by Raman Spectroscopic Polarization Measurements in HF Solution
- 1 January 1972
- journal article
- research article
- Published by SAGE Publications in Applied Spectroscopy
- Vol. 26 (1) , 77-80
- https://doi.org/10.1366/000370272774352533
Abstract
The vibrational assignments of the trifluorosulfur (IV) cation (SP3+, previously determined from spectra of solids, are confirmed by polarization measurements on solutions of SF3+BF4-, SF3+PF6-, and SF3+AsF6- in anhydrous HF. Techniques and equipment have been developed to obtain Raman spectra of species dissolved in anhydrous hydrogen fluoride. Accurate polarization information can be obtained even though the FEP fluorocarbon plastic used as a container and window material is optically active.Keywords
This publication has 9 references indexed in Scilit:
- Nuclear magnetic resonance investigation of complexes formed by arsenic pentafluoride and some very weak basesJournal of the American Chemical Society, 1970
- The trifluorosulphur(VI) oxide cation, SOF3 +Journal of the Chemical Society D: Chemical Communications, 1970
- An investigation of the structures of the adducts of SF4 with BF3, PF5, AsF5, and SbF5 in the solid state and in solution in HFCanadian Journal of Chemistry, 1969
- Raman Scattering and Band Assignments in PolytetrafluoroethyleneThe Journal of Chemical Physics, 1969
- Raman Apparatus Using Laser Excitation and Polarization Measurements. Rotational Spectrum of FluorineApplied Spectroscopy, 1969
- A laboratory distillation column for anhydrous hydrogen fluorideJournal of Physics E: Scientific Instruments, 1968
- Laser-excited Raman spectra of stretched polyethylene fibresChemical Communications (London), 1968
- Properties of SF4 and its adduct with BF3Journal of Inorganic and Nuclear Chemistry, 1958
- The Raman Spectrum, Structure, Force Constants, and Thermodynamic Properties of Bromine PentafluorideThe Journal of Chemical Physics, 1952