Reactivity of Pent-1-EN-4-Ynes and Synthesis of 2-Substituted Derivatives
- 1 April 1986
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 16 (5) , 603-609
- https://doi.org/10.1080/00397918608078779
Abstract
The synthesis of some 2-substituted pent-1-en-4-ynes via an SN 1 reaction is described. Using dicobalt octacarbonyl as protecting group, selective bromination of 1,5-diphenylpent-1-en-4-yne is achieved.Keywords
This publication has 9 references indexed in Scilit:
- Necic acid synthons. Part 4. Regioselectivity in the reactions of chloro and lodo derivatives of selected 3-hydroxy-2-methylenealkanoate esters with ethyl 2-methyl-3-oxobutanoateJournal of the Chemical Society, Perkin Transactions 1, 1985
- Synthesis of ethyl-α- propargyl acrylate - a useful five carbon synthonTetrahedron Letters, 1984
- Isolation of hypoxoside from hypoxis rooperi and synthesis of (E)-1,5-bis(3′,4′-dimethoxyphenyl)pent-4-en-1-ynePhytochemistry, 1984
- Separation of Acetylenic Prostaglandin Isomers as Cobalt ComplexesTetrahedron Letters, 1983
- Regio- and stereoselective synthesis of -1,3-enynes via coupling of nucleophiles with 1-[(alkynyl) dicobalt hexacarbonyl]allyl cationsTetrahedron Letters, 1982
- Reactions of vinylphosphonates. 2. Synthesis of functionalized dienes, trienes, and their analogs. Synthetic applications to regioselectively functionalized benzene derivativesThe Journal of Organic Chemistry, 1982
- Research on African medicinal plants—IITetrahedron, 1982
- Aromatic electrophilic substitution reactions of phenylmethylidynetricobalt nonacarbonyl and diphenylacetylenedicobalt hexacarbonyl. Preparatively useful reactions of coordinated organic ligandsJournal of the American Chemical Society, 1970
- Metalation reactions—VIIITetrahedron, 1970