Thermodynamic properties of fluid helium at high pressures determined from speeds of sound

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Abstract
The equation of state and heat capacity of fluid helium have been determined at temperatures from 98.15 to 298.15 K and at pressures from 100 to 1000 MPa using a new computational method. This is based on stepwise construction of ρT isobars starting from an experimental reference pρ isotherm and using the previously reported sound speed data of helium as a function of pressure and temperature. In the region of overlap, the calculated equation‐of‐state data show significant discrepancies from those obtained previously with direct measurements.