Nickel(0)-Mediated Sequential Addition of Carbon Dioxide and Aryl Aldehydes into Terminal Allenes
- 26 June 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 5 (15) , 2599-2601
- https://doi.org/10.1021/ol034480l
Abstract
Nickel-mediated sequential addition of carbon dioxide and aryl aldehydes into terminal allenes is reported. The reaction proceeded in a diastereoselective manner to afford α-methylene-γ-hydroxy carboxylic acids, which allowed stereoselective preparation of cis-β,γ-disubstituted α-methylene-γ-lactones.Keywords
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