Renormalization-group analysis of weak-flow effects on dilute polymer solutions
- 1 October 1986
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 34 (4) , 3362-3372
- https://doi.org/10.1103/physreva.34.3362
Abstract
A Gaussian polymer chain in the presence of hydrodynamic interactions and subjected to steady linear flows is investigated renormalization-group theoretically. To order ε (=4-d, d being the spatial dimensionality) and to the lowest nontrivial order in the flow strength, we consider the hydrodynamic effect on the mean-square end-to-end distance. From our general formula, we extract results for the physically interesting cases of shear and elongational flow. In the light of recent experimental results there is a possibility that the Gaussian model is of limited validity, even below the stretching transition.Keywords
This publication has 22 references indexed in Scilit:
- Hydrodynamic effect on the correlation functions of a gaussian polymer chainPhysics Letters A, 1985
- Time-dependent correlations of a self-avoiding polymer chainPhysics Letters A, 1985
- Unified description of temperature and concentration crossover in the excluded volume problem. 1. Osmotic pressure and correlation lengthsMacromolecules, 1984
- Theory of semi-dilute polymer solutions. I. Static property in a good solventJournal of Physics A: General Physics, 1983
- Application of field-theoretical renormalisation-group method to polymer dynamicsJournal of Physics C: Solid State Physics, 1982
- Polymer chain in good solvents under elongational flowJournal of Physics A: General Physics, 1982
- Scaling properties of the entropy of polymer solutionsJournal of Physics A: General Physics, 1981
- Conformational relaxation time in polymer solutions by elongational flow experiments: 1. Determination of extensional relaxation time and its molecular weight dependencePolymer, 1980
- The Lagrangian theory of polymer solutions at intermediate concentrationsJournal de Physique, 1975
- Exponents for the excluded volume problem as derived by the Wilson methodPhysics Letters A, 1972