Highly Helix-Sense-Selective Polymerization of Diphenyl-2-pyridylmethyl Methacrylate
- 5 November 1988
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 17 (11) , 1879-1882
- https://doi.org/10.1246/cl.1988.1879
Abstract
Asymmetric anionic polymerization of diphenyl-2-pyridylmethyl methacrylate by fluorenyllithium or N,N′-diphenylethylenediamine monolithium amide complex of (S)-(+)-2-(1-pyrrolidinylmethyl)pyrrolidine gave quantitatively an almost purely one-handed helical polymer with narrow molecular weight distribution.Keywords
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