Maximum in the translational energy dependence of the cross section for the Na+CH3I→NaI+CH3 reaction
- 15 December 1984
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 81 (12) , 5725-5729
- https://doi.org/10.1063/1.447623
Abstract
Relative values of the total reaction cross section for the crossed molecular beam reaction Na+CH3I→NaI+CH3 have been measured over the collision energy ET range of 0.11–0.40 eV. The measured excitation function is of a mechanistically bimodal type showing a maximum at ET ∼0.14 eV. This functionality is compared to those of closely related reactions and is discussed in the light of different dynamical models.Keywords
This publication has 20 references indexed in Scilit:
- On the collision energy dependence of the reaction cross sectionMolecular Physics, 1984
- Observed differential reaction cross section of the CH3I+Na→NaI+CH3systemMolecular Physics, 1983
- Collision energy dependence of the K+C2H5Br→BrK+C2H5reactionMolecular Physics, 1982
- Observed translational energy dependence of the K + C2H5I → KI + C2H5 reaction cross section from 0.17 to 0.55 eV (c.m.)Chemical Physics Letters, 1980
- Dynamical model for the “translational excitation features” in the atom—diatom reaction cross sectionChemical Physics, 1979
- Mechanism of Pd(II) reduction with benzene in sulfuric acid. π-Complexes of benzene with Pd(II) and Pd(I)Reaction Kinetics, Mechanisms and Catalysis, 1979
- Energy dependence of the cross section for alkali—methyl iodide reactionsChemical Physics Letters, 1977
- Energy dependence of the cross section for CH3I + K → CH3 + KI near thresholdChemical Physics Letters, 1976
- Idealized collision model for reactive scattering: Energy dependence of the cross section for CH3I + K → CH3 + KlChemical Physics Letters, 1975
- Molecular-Beam Kinetics: Reactions of Na with CH3I, Br2, and IClThe Journal of Chemical Physics, 1969