Synthesis and remarkable properties of iron β-polynitroporphyrins as catalysts for monooxygenation reactions
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 23-24
- https://doi.org/10.1039/c39940000023
Abstract
Two new porphyrins bearing several electron-withdrawing β-substituents were obtained in one step, in yields of about 50%, by nitration of meso-tetra(2,6-dichlorophenyl)porphyrin (TDCPPH2) and meso-tetrapentafluorophenylporphyrin (TFPPH2) with HNO3; the iron(III) complex of β-hexanitro-TDCPPH2 was a remarkable catalyst for the epoxidation of cyclooctene with diluted H2O2(complete conversion and 97% yield in 0.5 h) in the absence of any cocatalyst, and for the hydroxylation of alkanes, e.g. heptane, by O2.Keywords
This publication has 13 references indexed in Scilit:
- Activation of alkanes : the biomimetic approachCoordination Chemistry Reviews, 1993
- Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavageChemical Reviews, 1992
- Metalloporphyrins as models for the cytochromes p-450Coordination Chemistry Reviews, 1991
- Hydroxylation of linear alkanes catalysed by iron porphyrins: particular efficacy and regioselectivity of perhalogenated porphyrinsJournal of the Chemical Society, Chemical Communications, 1991
- Selective air oxidation of light alkanes catalyzed by activated metalloporphyrins - the search for a suprabiotic systemCoordination Chemistry Reviews, 1990
- Chemical model systems for drug‐metabolizing cytochrome‐P‐450‐dependent monooxygenasesEuropean Journal of Biochemistry, 1989
- Cytochrome P-450 and synthetic modelsPure and Applied Chemistry, 1987
- Metalloporphyrin Models for Cytochrome P-450Published by Springer Nature ,1986
- Sterically protected hemins with electronegative substituents: efficient catalysts for hydroxylation and epoxidationJournal of the Chemical Society, Chemical Communications, 1984
- NIH shift in haemin–iodosylbenzene-mediated hydroxylationsJournal of the Chemical Society, Chemical Communications, 1981