Temperature dependence of V → R, T energy transfer probabilities in CO2(00°1) + HF/DF
- 1 March 1974
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 60 (5) , 2167-2168
- https://doi.org/10.1063/1.1681329
Abstract
Temperature dependence of vibration to rotation‐translation energy transfer probabilities in CO2(00°1)+HF/DF→CO2(n m l0) + HF/DF has been investigated in the range 300–1000°K. It is shown that the negative temperature dependence of transition probabilities at lower temperatures and the appearance of the probability minimum at intermediate temperatures are due to the influence of hydrogen bond interaction.Keywords
This publication has 9 references indexed in Scilit:
- Temperature dependence of vibrational relaxation in the HF, DF, HF–CO2, and DF–CO2 systemsThe Journal of Chemical Physics, 1974
- Vibration-to-rotation energy transfer in hydrogen fluoride: Effects of the dipole-dipole and hydrogen-bond interactionsThe Journal of Chemical Physics, 1973
- Temperature dependence of V-V and V-R, T energy transfer measurements in mixtures containing HFThe Journal of Chemical Physics, 1973
- De-excitation of CO2(00°1) by Hydrogen FluoridesThe Journal of Chemical Physics, 1972
- Vibrational Energy Transfer and De-excitation in the HF, DF, HF–CO2, and DF–CO2 SystemsThe Journal of Chemical Physics, 1972
- Laser-Excited Vibrational Relaxation Studies of Hydrogen FluorideThe Journal of Chemical Physics, 1972
- Vibrational Deactivation of CO2 by HF and DF at 75 and 100°CThe Journal of Chemical Physics, 1972
- De-Excitation of molecular vibration on collision: vibration-to-rotation energy transfer in hydrogen halidesThe Journal of Physical Chemistry, 1971
- HF·SO2 and similar vapor phase complexesJournal of Molecular Spectroscopy, 1959