Organotin biocides. Part 8. The crystal structure of triphenyltin formate and a comparative variable-temperature tin-119 Mössbauer spectroscopic study of organotin formates and acetates
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 1,p. 101-106
- https://doi.org/10.1039/dt9870000101
Abstract
The structure of triphenyltin formate has been determined by an X-ray study. Crystal data: monoclinic, space group B21/a, a= 20.176(8), b= 15.539(6), c= 21.952(10)Å, β= 90.30(6)°, Z= 16. The geometry about tin is trigonal bipyramidal with a trans-O2SnR3 stereochemistry (R = Ph), leading to a chain polymeric structure for the lattice. The geometric distortions which accompany polymer formation are assessed, and used to interpret variable-temperature Mössbauer spectroscopic data for triphenyl-, tricyclohexyl-, and trimethyl-tin formates and acetates.This publication has 3 references indexed in Scilit:
- Notes. Tin-119 and nitrogen-14 nuclear magnetic resonance and tin-119 variable-temperature Mössbauer spectroscopic study of tricyclohexyltin isothiocyanate including the first observation of resolved117,119Sn–14N coupling in an organotin compoundJ. Chem. Soc., Dalton Trans., 1986
- Organotin biocides. Part 2. Variable-temperature119Sn Mössbauer study of phenyl- and cyclohexyl-tin compoundsJ. Chem. Soc., Dalton Trans., 1985
- Structure-activity relationships in triorganotin biocides: The influence of the anionic radicalPesticide Science, 1984