Modified Monoterpenes from Biotransformation of (−)-Isopiperitenone by Suspension Cell Culture of Mentha piperita
- 24 February 1998
- journal article
- review article
- Published by American Chemical Society (ACS) in Journal of Natural Products
- Vol. 61 (3) , 354-357
- https://doi.org/10.1021/np970388k
Abstract
The biotransformation of (−)-(4R)-isopiperitenone (1) by suspension cell culture of Mentha piperita yielded three new hydroxylated derivatives, 4−6, and two new epoxidized derivatives, 7 and 8. (−)-7-Hydroxyisopiperitenone (2) and its glucoside were previously isolated from the culture. The structures of 4−8 were elucidated using spectral methods, and their absolute stereochemistry was established by NMR experiments and correlation with compounds of known configuration.Keywords
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