Crystal and molecular structure of the dimeric complex [{Cd[Zr2(OPri)9](η-Cl)}2]
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 738-739
- https://doi.org/10.1039/c39910000738
Abstract
The product of the (1 : 1) reaction between CdCl2 and K[Zr2(OPri)9] in benzene is the dimeric species [{Cd[Zr2(OPri)9](µ-Cl)}2], the first (chloro)alkoxometallate derivative to be characterized by X-ray crystallography.Keywords
This publication has 25 references indexed in Scilit:
- Synthesis, structural principles and reactivity of heterometallic alkoxidesChemical Reviews, 1990
- Chemistry of alkoxide precursorsJournal of Non-Crystalline Solids, 1990
- Synthesis and reactions of metal alkoxidesJournal of Non-Crystalline Solids, 1988
- Chloride and alkoxide alkoxometallates and termetallic isopropoxides of copper(II)Journal of Organometallic Chemistry, 1988
- Synthesis and characterization of novel tri‐ and tetra metallic isopropoxides of later “3d” metalsRecueil des Travaux Chimiques des Pays-Bas, 1988
- Preparation and crystal structure of the addition compound MeLi·U[OCH(CMe3)2]4, a compound with a uranium to carbon σ-bondJournal of the Chemical Society, Chemical Communications, 1987
- Synthesis of novel termetallic isopropoxidesPolyhedron, 1985
- Dinuclear uranium alkoxides. Preparation and structures of KU2(OCMe3)9, U2(OCMe3)9, and U2(OCHMe2)10, containing [uranium(IV), uranium(IV)], [uranium(IV), uranium(V)], and [uranium(V), uranium(V)], respectivelyInorganic Chemistry, 1984
- Transition-Metal AlkoxidesPublished by Elsevier ,1983
- Faster data collection without loss of precision. An extension of the learnt profile methodActa Crystallographica Section A, 1981