THE SOLVENT ISOTOPE EFFECT AND THE PARTIAL MOLAR VOLUME OF IONS
- 15 February 1966
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 44 (4) , 487-494
- https://doi.org/10.1139/v66-065
Abstract
The partial molar volume of ions in water furnishes an indication, if not precise information, about the nature of ionic solvation (1–5). Accordingly, it was hoped that differences in this term and particularly the effect of temperatures on the differences in the apparent partial molar volume for a series of ions in light and heavy water would provide a basis for decisions on the nature of solvation of the benzenesulfonic ion. This ion is of considerable interest in the study of solvolysis, but very little is known about the characteristics of solvation.Keywords
This publication has 23 references indexed in Scilit:
- Dilatometric measurements of apparent molar volumes of dilute aqueous electrolytesTransactions of the Faraday Society, 1965
- THE ACTIVATION PROCESS IN SOLVOLYSISCanadian Journal of Chemistry, 1964
- VOLUME CHANGES ON MIXING SOLUTIONS OF SODIUM CHLORIDE, HYDROCHLORIC ACID, SODIUM PERCHLORATE, AND PERCHLORIC ACID AT CONSTANT IONIC STRENGTH. A TEST OF YOUNG'S RULE1The Journal of Physical Chemistry, 1963
- Initial-state and Transition-state Isotope Effects of Methyl Halides in Light and Heavy Water1-3Journal of the American Chemical Society, 1962
- The nature of the structure difference between light and heavy water and the origin of the solvent isotope effect—ITetrahedron, 1960
- Hydrolysis of Alkyl Halides and Sulfonium Salts by Light and Heavy Water1Journal of the American Chemical Society, 1955
- Pressure-Volume-Temperature Relations in Solutions. IV. The Apparent Volumes and Thermal Expansibilities of Sodium Chloride and Sodium Bromide in Aqueous Solutions between 25 and 95°Journal of the American Chemical Society, 1941
- A Graduated PycnometerIndustrial & Engineering Chemistry Analytical Edition, 1939
- The Viscosity of Aqueous Solutions of Electrolytes as a Function of the Concentration. V. Sodium ChlorideJournal of the American Chemical Society, 1937
- The Apparent Molal Heat Capacity, Volume, and Compressibility of Electrolytes.Chemical Reviews, 1933