Order and Low Dimensionality in the Organic Superconductor (BEDT-TTF) 2 Cu(NCS) 2 Revealed by STM
- 15 May 1992
- journal article
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 256 (5059) , 1012-1014
- https://doi.org/10.1126/science.256.5059.1012
Abstract
Single-crystal samples of [(BEDT-TTF)(2)]+[Cu(NCS)(2)]-were synthesized and studied with a scanning tunneling microscope (STM). Real-space images of the anion and cation surfaces with molecular resolution were obtained. The images show no evidence of structural disorder or stacking faults previously suggested. The presence of an additional modulation commensurate with the lattice provides evidence of a lattice distortion. The cause of this modulation is unknown. The presence of a charge density wave in the material would have implications on the dimensionality of the material that may explain the peculiar temperature dependence of the electrical conductivity. This interpretation is consistent with the calculated Fermi surface, which allows nesting of the wave vector.Keywords
This publication has 15 references indexed in Scilit:
- Electronic structure of the organic superconductor κ-(BEDT-TTFCu(NCS[where BEDT-TTF is bis(ethylenedithio)tetrathiafulvalene] studied by scanning tunneling microscopyPhysical Review B, 1991
- Scanning tunneling microscopy/scanning tunneling spectroscopy of the organic superconductors (TMTSF)2-PF6 and (TMTSF)2-ClO4Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, 1991
- Tensile stress effect on transport properties of (BEDTTTF)2Cu(NCS)2Solid State Communications, 1990
- Pressure dependence of the transport properties of the molecular superconductor, κ-(BEDT TTF)2Cu(NCS)2Journal of Physics: Condensed Matter, 1989
- Structural Evidence of Charge Density Waves in the Series of Molecular Conductors and Superconductors: TTF(M(dmit) 2 ) 2 (M = Pd, Ni)Europhysics Letters, 1989
- Shubnikov-de Haas effect and the fermi surface in an ambient-pressure organic superconductorCuPhysical Review B, 1988
- Apparent barrier height in scanning tunneling microscopyPhysical Review B, 1988
- Theory of the scanning tunneling microscopePhysical Review B, 1985
- Theory and Application for the Scanning Tunneling MicroscopePhysical Review Letters, 1983
- Neutron-Scattering Study of the 38- and 54-K Phase Transitions in Deuterated Tetrathiafulvalene- Tetracyanoquinodimethane (TTF-TCNQ)Physical Review Letters, 1975