A review of ultrashort pulsed laser ablation of materials

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Abstract
The use of ultrashort pulsed lasers in materials processing is an emerging technology. These lasers have the capability to ablate materials precisely with little or no collateral damage, even with materials that are impervious to laser energy from conventional pulsed lasers. The extreme intensities and short timescale at which ultrashort pulsed lasers operate differentiate them from other lasers. The means of ultrashort pulsed laser generation is discussed; included are a survey of pulse compressor techniques with solid state lasers and a brief discussion of excimer-dye lasers. This is followed by a discussion of specific examples of ultrashort pulsed machining of specific materials, along with mechanistic details. Optical breakdown mechanisms, including electron avalanche ionization and multiphoton absorption are discussed. It is shown that as pulse width increases and intensity decreases, laser damage becomes a stochastic process in which the ultrashort pulsed, high intensity light causes optical breakdown over a very narrow range. This, along with the lack of significant thermal conduction, greatly improves the precision of ultrashort pulsed lasers in micromachining applications.